钙同位素地球化学研究新进展及其在碳酸岩-共生硅酸盐研究中的应用     

向蜜  龚迎莉  刘涛  田世洪 《地质学报》2021,95(12):3937-3960

作为"非传统稳定同位素"家族成员,钙同位素正受到国际地学界日益广泛的关注.钙是主要的造岩元素,也是生物必需的元素.钙在地球各圈层广泛分布,研究钙同位素的地球化学行为将有助于提高我们对各种生物过程和地质过程的认识.钙同位素测定主要采用热电离质谱仪(TIMS)和多接收电感耦合等离子体质谱仪(MC-ICP-MS),分别表示为δ44/40 Ca和δ44/42Ca.目前自然界可观测到的δ44/40Ca变化范围为-2.0‰～6.75‰,约8.7‰.本文系统介绍了近年来钙同位素分析中样品溶解、化学分离、质谱测定以及高温地质过程中的钙同位素分馏及其地质应用等方面的研究成果,尤其对钙同位素在碳酸岩-共生硅酸盐岩研究中的意义、钙同位素组成以及取得的主要认识作了较为全面的介绍.阐述了放射成因40 Ca、部分熔融作用/分离结晶作用、地壳同化作用、古俯冲碳酸盐循环、热液蚀变作用、岩浆起源深度等对碳酸岩、硅酸盐岩的钙同位素组成造成的影响.最后,通过系统对比碳酸岩-共生硅酸盐岩的锂、镁、钙同位素研究成果,认为应该开展多元同位素体系的联合示踪.由于不同同位素体系存在相似性和差异性,而多元同位索体系相结合能有效地加强优势互补,将是同位素地球化学研究发展的一种必然趋势.  相似文献   

山西长治盆地中更新世气候转型期环境变化特征     

李金秋  李向全  范保硕  王振兴  李月丛  刘林敬  侯新伟  张春潮 《地质学报》2021,95(11):3532-3543

中更新世气候转型(MPT)是第四纪环境变化的一个重要时期,该时期气候模式、气候周期等均发生了明显变化,然而不同区域对中更新世气候转型的响应特征存在明显差异.本研究选取了长治盆地XZK4钻孔中更新世转型前后(1.8～0.1 Ma)共207个样品,通过古地磁定年,运用粒度端元分析和孢粉分析,阐述了长治盆地中更新世转型期的环境变化与湖泊演化特征.结果显示,1.8 Ma以来,孢粉组合中乔木花粉含量多高于60％,但个别时段草本植物花粉占优,显示区域植被多数阶段为森林,但存在明显冷期,并且1.1 Ma和0.55 Ma是研究区环境转变的重要转折点.中更新世转型期前(～1.1 Ma):沉积物粒度总体较细,黏土含量多高于25％,EM1组分(湖相沉积)多高于60％,EM3(河流相组分)在个别时段出现,总体显示该阶段沉积物组成以湖相沉积为主,个别阶段受到河流影响大;中更新世转型时期(1.1～0.55 Ma):沉积物粒度较上一阶段更细,黏土含量(平均为30％)、EM1占比和孢粉浓度均达到研究段最高,沉积物颜色以棕灰色为主,EM3组分占比降至最低,其中1.1～0.95 Ma喜冷的云杉属花粉出现,显示该时期研究区气候总体偏冷湿,湖泊面积较1.1 Ma之前扩大;中更新世转型后(～0.55 Ma):沉积物粒度明显变粗,达到钻孔最高值,沉积物颜色变黄,EM2(风成组分)和EM3占主导,草本植物含量增加,尤其是喜干的蒿属花粉增加明显,表明气候较之前变干,沉积物类型以风力沉积为主,湖泊消亡.综合对比显示,构造运动是影响长治古湖消长的主要驱动力,气候变干加剧了湖泊消亡.  相似文献   

降水现象仪观测应用评估   总被引：1，自引：0，他引：1       下载免费PDF全文

杜传耀  尹佳莉  李林  伍永学  姜涛 《气象》2019,45(5):730-737

利用2017年9月至2018年8月北京20个站降水现象仪采集数据与人工平行观测数据,对降水现象仪进行了对比评估。结果表明:降水现象仪的缺测率为0.01%,空报率为0.6%,捕获率为93.5%,漏报率为27.9%,错报率为10.0%。从统计结果可知,降水现象仪的缺测率、空报率较低,捕获率较高,体现出设备性能良好的一面,漏报率和错报率偏高,表明设备漏识别和错误识别的情况较多,漏报主要发生在弱降水过程中,错报主要出现在毛毛雨的识别上。设备测量和人工观测降水开始时间一致性较好,终止时间一致性偏差;降水现象仪现存问题:在大雨强时易出现雨滴叠加误识别,在小雨强时识别率会降低,在无降水错误输出降水现象方面缺少质控。  相似文献   

基于波导结构的紧凑型电介质加载双极化天线研究     

马自龙  褚庆昕 《南京气象学院学报》2019,11(1):17-22

本文提出了一款基于波导结构的紧凑型电介质加载双极化天线.通过采用在传统波导内加载电介质材料的方法,可以有效减小波导尺寸,从而达到天线小型化的目的.针对波导结构口径天线高后瓣辐射的问题,本文提出了一种在波导金属壁上添加矩形槽孔的方法,该方法的原理不同于扼流环结构.相比之下,矩形槽孔具有结构简单、尺寸小、加工方便等优点.通过电磁场全波仿真分析,可以发现所提出的天线具有阻抗带宽宽（大于40%）、增益高（8.6±0.6 dBi）、辐射性能稳定等优点,有很大的潜力,可以应用在如卫星通信等X波段的各种应用场景中.  相似文献   

94/220 GHz星载雷达双波长比对非球形冰晶云参数敏感性分析          下载免费PDF全文

吴举秀  窦芳丽  安大伟  顾瑜  周青  刘伟 《气象学报》2019,77(3):529-540

利用不同形状冰晶的散射特性,获得了非球形冰晶云的94/220 GHz测云雷达双波长比,探讨了非球形冰晶云的双波长比与云内微物理参数的关系,分析了衰减前后的星载雷达反射率因子及双波长比的垂直廓线。结果表明:（1）双波长比可以反映小到0.1 mm中值尺度的冰粒子,对粒子总数、谱的形状参数不敏感,对粒子大小、形状、云衰减较敏感。（2）雷达灵敏度一定时,星载雷达可测云厚与雷达波长、冰含水量（IWC）的垂直分布、云厚及衰减有关;没有进行衰减订正时,双波长比和衰减有关,冰含水量越大,波长越短,衰减越大,双波长比最大值与可探测云厚有关。两部雷达可探测冰含水量为0.001—0.1 g/m3、厚2 km的冰云;当云厚5 km、冰含水量垂直分布在0.001—0.2 g/m3时,云厚的94%基本可以被220 GHz云雷达探测到。（3）如果两部雷达气象方程中用水的介电因子,测量回波强度应进行介电因子的订正后再计算双波长比。   相似文献   

一次拖曳型飑线过程雨滴谱演变特征研究          下载免费PDF全文

王俊  刘畅 《山东气象》2019,39(2):43-57

利用Thies激光雨滴谱仪观测资料和CINRAD/SA多普勒雷达观测资料,分析了2017年7月18日一次典型中纬度拖曳型飑线过程不同发展阶段雨滴谱和积分参数的演变特征,主要结果为：1）成熟飑线回波包括对流带、过渡区和拖曳层状云区三部分,对流带前侧不断有对流带生成并合并到主对流带中,使得对流带的前沿具有强的反射率因子,并且有多个雨强大值中心。2）垂直穿过飑线对流带,雨强增加阶段有较少的小粒子（直径小于1 mm）和特大粒子（直径大于5 mm）,以及较低的雨滴浓度和反射率因子,而雨强减弱阶段有较多的小粒子和特大粒子,以及较高的雨滴浓度和反射率因子;飑线加强阶段,雨滴谱有较大的峰值直径（0.44 mm）、较多的大（直径大于3 mm）和特大粒子,而飑线减弱阶段,雨滴谱有较小的峰值直径（0.19 mm）、较少的大粒子。3）对流带、过渡区和层状云降水雨滴谱的Gamma谱三参数N0、μ、λ随雨强增大有明显的分层特征,相同雨强时,对流云和过渡区降水的三参数比层状云降水的数值大;而飑线不同发展阶段、不同降水类型的λ-μ关系具有一致性,二次多项式可以很好地拟合λ-μ关系。4）归一化雨滴谱参数NW和D0的分布可以用来区分对流云和层状云降水,并给出了新的分离线方程;另外,飑线在发展和减弱阶段的雨滴谱特征有明显差异,表明飑线演变过程降水形成的微物理机制发生变化,前期冷云过程有重要影响,而后期暖云过程起主导作用。  相似文献   

Changeability of Movable Bed‐Surface Particles in Natural,Gravel‐Bed Channels and Its Relation to Bedload Grain Size Distribution (Scott River,Svalbard)          下载免费PDF全文

Waldemar Kociuba  Grzegorz Janicki 《Geografiska Annaler: Series A, Physical Geography》2015,97(3):507-521

The presented paper analyses the variability of grain size distribution parameters of bedload transported by the gravel‐bed Scott River (Svalbard) draining a glacier catchment with an area of 10 km². The grain size distribution analysis is one of the basic elements of identification of the fluvial transport mechanisms in gravel‐bed rivers. It is used for the determination of threshold values for bedload movement. It is also treated as an important indicator of the origin, routes of distribution, and conditions of transport and deposition of fluvial bedload. The field study in a natural proglacial gravel‐bed channel was carried out at two reaches in the mouth section of Scott River. The study revealed relatively high temporal variability and similar mean parameters of grain size distribution in conditions of low discharges. Bedload transport rates reached a mean of 71.9–76.0 kg d^?1 in channel cross‐section. Bedload texture was dominated by gravels with a proportional contribution of the fine‐grained fraction along with very fine‐grained gravels (8‐2 mm) of 38.8%. The medium‐grained fraction (16‐8 mm) constituted 33.7%, with a lower contribution from the coarse‐grained fraction (32‐16 mm) of 23.2%, and the very coarse‐grained fraction (64‐32 mm) of 4.4%. Two periods in the course of bedload transport and distribution of grain size distribution parameters were distinguished based on variation of hydro‐meteorological conditions. The first half of the measurement period was distinguished by significantly higher values of daily loads and increased contribution of the coarse‐grained and very coarse‐grained fraction (28–31% and 6.2–6.6%, respectively). During this time, the river discharged up to 94% of bedload. This resulted in a clear tendency for riverbed scouring. The second half was distinguished by generally low daily bedload transport rates (<10 kg d^?1), an increase in contribution of fine‐ and very fine‐grained gravels (42–55.6%), and a change in the tendency to aggradation. Grain size indices were more varied, and grains were usually finer and better sorted. Selective transport processes, often related to redeposition, were dominant in the channel. Along with an increase in flow velocity, conditions for material deposition became more variable. This was manifested in weaker sorting and an increase in grain diameter.  相似文献   

常用锂同位素地质标准物质的多接收器电感耦合等离子体质谱分析研究   总被引：3，自引：3，他引：0  

赵悦  侯可军  田世洪  杨丹  苏嫒娜 《岩矿测试》2015,34(1):28-39

锂同位素研究是非传统稳定同位素地球化学研究的前沿,已广泛应用于从地表到地幔的岩石圈及流体等固体地球科学的研究领域。准确测定锂同位素比值是应用该同位素体系的前提。本文报道了国际上7种常用地质标准物质(BHVO-2、JB-2、BCR-2、AGV-2、NKT-1、L-SVEC、IRMM-016)的锂同位素组成数据。分析中采用硝酸-氢氟酸混合酸消解岩石标准样品,通过3根阳离子交换树脂(AG50W-X8,200~400目)填充的聚丙烯交换柱和石英交换柱对锂进行分离富集,利用Neptune型多接收器电感耦合等离子体质谱(MC-ICPMS)测定锂同位素比值,使用标准-样品交叉法(SSB)校正仪器的质量分馏。实验得到这7种常用地质标准物质的锂同位素组成与测试精度(2SD)分别为:δ7LiBHVO-2—L-SVEC=4.7‰±1.0‰(n=53),δ7LiJB-2—L-SVEC=4.9‰±1.0‰(n=20),δ7LiBCR-2—L-SVEC=4.4‰±0.8‰(n=8),δ7LiAGV-2—L-SVEC=6.1‰±0.4‰(n=14),δ7LiNKT-1—L-SVEC=9.8‰±0.2‰(n=3),δ7LiL-SVEC—L-SVEC=-0.3‰±0.3‰(n=10),δ7LiIRMM-016—L-SVEC=0.0‰±0.5‰(n=10),这些数据在误差范围内与国际上已发表的数据一致。Li同位素分析精度可以达到大约0.5‰,长期的分析精度即外部重现性≤±1.0‰,达到了国际同类实验室水平。7种常用地质标准物质的锂同位素组成数据的发表为锂同位素研究提供了统一的标准,使地质样品的锂同位素数据的质量监控成为可能。在基质效应的研究中,使用不同量的IRMM-016配制的标准溶液过柱,深入探讨了样品量对锂同位素测定值的影响,结果表明,在现有测试精度下,只要分析样品的锂含量达到100μg/L,且不超过树脂的承载量,样品的锂同位素组成在误差范围内与真值吻合,样品量的大小不影响锂同位素测定结果的准确性。  相似文献   

Carbon isotope fractionation of Thermoanaerobacter kivui in different growth media and at different total inorganic carbon concentration     

《Organic Geochemistry》2015

Chemolithotrophic homoacetogenic bacteria apparently express a characteristic stable carbon isotope fractionation and may contribute significantly to acetate production in anoxic environments. However, fractionation factors (ε) in bacterial cultures have rarely been determined and the effect of substrate availability has not been assessed. We therefore studied the kinetic carbon isotope effect in cultures of Thermoanaerobacter kivui grown at 55 °C. The fractionation factor in HCO₃⁻ buffered medium was ca. 15‰ more negative than that in PO₄³⁻ buffered medium. To test whether the difference was caused by the initial substrate ratio of H₂ and total inorganic carbon (TIC; 0.5 in HCO₃⁻ vs. 4.0 in PO₄³⁻ buffered medium), T. kivui was grown in either [3-(N-morpholino) propanesulfonic acid, MOPS] buffered or PO₄³⁻ buffered media with different HCO₃⁻ concentration. Indeed, the fractionation factor became more negative with increasing HCO₃⁻ concentration and decreasing H₂/TIC ratio. While pH had only a small effect, the fractionation was generally more negative in MOPS buffered than in phosphate buffered media, indicating that the buffer system also affected fractionation. Collectively, the results show that substrate availability and other environmental factors affect the magnitude of isotope fractionation during acetate production by chemolithotrophic homoacetogenesis.  相似文献   

New material of the large-bodied caenagnathid Caenagnathus collinsi from the Dinosaur Park Formation of Alberta,Canada     

《Cretaceous Research》2015

A reexamination of large caenagnathid material from the Upper Cretaceous (Campanian) Dinosaur Park Formation of Alberta, Canada, reveals undescribed material referable to Caenagnathus collinsi. A femur, two astragalocalcanei, two metatarsals, two unguals, and a caudal vertebra provide anatomical information on Caenagnathus collinsi. Estimates of femoral length based on the proportions of other oviraptorids suggest that the non-femoral material represents a taxon intermediate in size between Chirostenotes pergracilis from the Dinosaur Park Formation and Anzu wyliei from the Maastrichtian Hell Creek Formation. The femur is within the range of predictions, and confirms the body size estimates based on the other material. The large size of the material and a number of morphological characters distinguish the material from Chirostenotes pergracilis and suggest that it is referable to Caenagnathus collinsi. The relative diversity of caenagnathids in the Dinosaur Park Formation is likely underestimated.  相似文献